Electronegativity: An Atom’s Pull on Electrons

Electronegativity is a measure of an atom’s ability to attract shared electrons toward itself in a chemical bond. It reflects how strongly an atom “pulls” on electrons when it forms molecules with other atoms.

In the periodic table, electronegativity generally:

  • Increases across a period (left to right), as atoms have more protons and a stronger pull on electrons
  • Decreases down a group (top to bottom), as outer electrons are farther from the nucleus and more shielded

The most electronegative element is fluorine, assigned a value of 3.98 on the Pauling scale.

Electronegativity differences between atoms determine the type of bond:

  • Small or no differencenonpolar covalent bond
  • Moderate differencepolar covalent bond
  • Large differenceionic bond

Understanding electronegativity is crucial for predicting molecular polarity, reactivity, and bond strength, making it a central concept in chemical bonding and molecular behavior.

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